It has also been used to make bile acids, cholesterol and steroids. Phytochemistry. The present invention also addresses the problem of providing an imaging element, a light sensor, and a compound. Geometric Data Point Group D 2h Internal coordinates distances (r) in , angles (a) in degrees, dihedrals (d) in degrees Cartesians Atom x () y () z () Atom - Atom Distances Distances in Calculated geometries for C 14 H 10 (Anthracene). ;jC'g HmNl$^6FYfc f:pNuo#w'e#=&sqd$ndMf x?3lQUPI6p8hbu}j0Qamysp=o|ULz$4Bhx7MG~Ja)?2?*~x> gyVrzNf|rY(n!C/j6N> ndpFMYm4=6Ml21tl?~]>:-~p tvhQWuNnTm&QGEv{+7"{s3G?oR3>?K7(/~]Ep0n0YzRJ^KvWMup?
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xntluww#!4l [25] Grignard reagents may be similarly titrated.[26]. Be the first to rate this page. 2016 Apr;149:130-6. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Would you like email updates of new search results? Uses advised against Food, drug, pesticide or biocidal product use. Product Classification |
; Ding, S.F. Chemosphere. [13]
Sun K, et al. Biological evaluation, molecular modeling and dynamics simulation of phenanthrenes isolated from Bletilla striata as butyrylcholinesterase inhibitors. Product Line. Biologically Active Compounds |
except for the exhibition of a hydroxyl group at C-6, instead of a methoxy group. SAFETY DATA SHEET Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1. Organic Compound; Aromatic Hydrocarbon; Industrial By-product/Pollutant; Polycyclic Aromatic Hydrocarbon; Pollutant; Food Toxin; Industrial/Workplace Toxin; Natural Compound, ORL-MUS LD50 700 mg kg-1, IPR-MUS LD50 700 mg kg-1, IVN-MUS LD50 56 mg kg-1, Harmful/Irritant/Light Sensitive/Store under Argon, Toxic to aquatic life/Harmful/Irritant/Light Sensitive/Store under Argon, WARNING: Irritates skin and eyes, harmful if swallowed, A polycyclic aromatic hydrocarbon composed of three fused benzene rings which takes its name from the two terms 'phenyl' and 'anthracene. Chromatogr., 17, 1965, 50-59. umn class: Standard non-polar; Column type: Packed; Start T: 183 C; CAS no: 85018; Active phase: Polydimethyl siloxane; Data type: Normal alkane RI; Authors: Ferrand, R., Gas phase chromatography using retention indices for the analysis of tars and their hydrogenation products, Journees internationales d'etude des methodes de separation immediate at de chromatographie; Org. A classic and well established explanation is based on Clar's rule. Dupuy J, et al. All except the last one, cyclopenta [ a ]phenanthrene are trivial retained names, this one is systematically created name (P-25). Subcellular distribution and biotransformation of phenanthrene in pakchoi after inoculation with endophytic Pseudomonas sp. 7 0 obj
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Z=#O?= 78qN_T,MOw{|l>>%/qp{gw`g?zx~Oe.}Yib.Y7(:B~. Display controls: Jmol.jmolLink(jmolApplet0,"select all;spacefill 100%; wireframe off;","Spacefill") ; Yi, L.-Z. Try now! Commonly, humans are exposed to phenanthrene through inhalation of cigarette smoke but there are many routes of exposure. (Bacillus sp.195%, Bacillus velezensis90%, Bacillus megaterium91% . stream
; Yung, I.K.S. ; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Each point on the graph represents mean SD (n = 3 . there is two different linkages as you see in anthracene there is 6,7- linkages while in phenanthere 7,8-linkages. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. inhabited the phyllosphere of ornamental plants grown in urban polluted areas. Journals |
%&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz What are isomers? The phenanthrene is a leaf-like crystal with a relative density of 1.179 (25/4 ) and a refractive index of 1.6450, melting point of 101 C and boiling point of 340 C. Reference Material Type. 1996, 100, 15358-15367, M Gussoni, R Rui, G Zerbi "Electronic and relaxation contribution to linear molecular polarizability. <<
PAHs Stable. It has also been used to make bile acids, cholesterol and steroids. ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. ; Lind, M.A., Gas-liquid chromatographic analyses. endobj
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; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. w !1AQaq"2B #3Rbr : AC130090000; AC130090050; AC130090500; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals. /MediaBox [0 0 612 792]
[1]. [emailprotected], We gratefully acknowledge support from the UK Physical Sciences Centre, HEA (National Teaching Fellowship), JISC, Faculty of Science TQEF and EPSRC. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C 14 H 10, consisting of three fused benzene rings. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 5 K/min; Start T: 80 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. stream
447 (1998) 163-215, Frenkel, M; Marsh, K.N. Phenanthrene Dimers: Promising Source of Biologically Active Molecules. Monoisotopic mass 178.078247 Da. [3][4] It is often sold as the monohydrate. Liu Y, Tu Y, Kang Y, Zhu C, Wu C, Chen G, Liu Z, Li Y. Sci Rep. 2022 Aug 11;12(1):13649. doi: 10.1038/s41598-022-17912-7. Chem., 66, 1994, 1799-1807. ass: Standard non-polar; Column length: 2 m; Column type: Packed; Heat rate: 5 K/min; Start T: 120 C; End T: 260 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Substrate: Uniport HP; Data type: Normal alkane RI; Authors: Onodera, S.; Igarashi, K.; Fukuda, A.; Ouchi, J.; Suzuki, S., Chemical changes of organic compounds in chlorinated water. ?7?6MM58VK==K This website collects cookies to deliver a better user experience. Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Phenanthrene is more stable than its linear isomer anthracene. Food Chem., 4(2), 2005, 899-915. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. Jmol.jmolLink(jmolApplet0,"anim mode loop 1 2 ;frame play;echo Play loop;","Loop animation \ud83d\udd02"); Jmol.jmolLink(jmolApplet0,"anim off;echo ","Stop animation \u23F9"); Jmol.jmolLink(jmolApplet0,"anim rewind#;","Frame 1 \u23EB");Jmol.jmolHtml(' ') [11] It is found in small amounts among a few coal burning sites. Buying Leads |
[3] However, according to IARC, it is not identified as a probable, possible or confirmed human carcinogen.[4]. as probed using HRMS coupled with isotope-labeling. Morphine, a hydrophilic phenanthrene derivative, is the prototypical opioid against which all other opioids are compared for equianalgesic potency. Food Chem., 49, 2001, 192-202. ass: Standard polar; Column length: 3.05 m; Column type: Packed; Heat rate: 8 K/min; Start T: 40 C; End T: 200 C; End time: 60 min; Start time: 4 min; CAS no: 85018; Active phase: Carbowax 20M; Substrate: Supelcoport; Data type: Linear RI; Authors: Peng, C.T. [7] It is used as a redox indicator with standard potential +1.06 V. The reduced ferrous form has a deep red colour and the oxidised form is light-blue. Res. Chromatogr., 173, 1979, 109-118. ass: Semi-standard non-polar; Column diameter: 0.28 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.17 um; Data type: Linear RI; Authors: Lee, M.L. Educ., 76(12), 1999, 1695-1696. class: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Description: 50C(2min)=>(20C/min)=>120C=>(7C/min)=>310C(10min); CAS no: 85018; Active phase: 5 % Phenyl methyl siloxane; Carrier gas: He; Phase thickness: 0.52 um; Data type: Linear RI; Authors: Yasuhara, A.; Shiraishi, H.; Nishikawa, M.; Yamamoto, T.; Uehiro, T.; Nakasugi, O.; Okumura, T.; Kenmotsu, K.; Fukui, H.; Nagase, M.; Ono, Y.; Kawagoshi, Y.; Baba, K.; Noma, Y., Determination of organic components in leachates from hazardous waste disposal sites in Japan by gas chromatography-mass spectrometry, J. Chromatogr. Aquat. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 15 m; Column type: Capillary; Heat rate: 50 K/min; Start T: 50 C; End T: 320 C; End time: 1 min; Start time: 0.5 min; CAS no: 85018; Active phase: CP Sil 8 CB; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vreuls, R.J.J. [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. Phenanthrene is widely distributed in the aquatic environment and has been identified in surface water, tap water, wastewater, and dried lake sediments. ; Lind, M.A., Gas-liquid chromatographic analyses. 148 A dihydronaphthalene 270 with a . /Type/Page
Quality Level. ; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase, J. Molecular Targets and Mechanisms of 6,7-Dihydroxy-2,4-dimethoxyphenanthrene from Chinese Yam Modulating NF-B/COX-2 Signaling Pathway: The Application of Molecular Docking and Gene Silencing. The BardhanSengupta phenanthrene synthesis is a classic way to make phenanthrenes.[5]. ; Yang, H.; Fang, H.-Z. dust mask type N95 (US);Eyeshields;Gloves, 2902909090 other aromatic hydrocarbonsSupervision conditions:NoneVAT:17.0%Tax rebate rate:9.0%MFN tariff:2.0%General tariff:30.0%, METHYLENE CHLORIDE IN THE STANDARD MATERIAL OF THE PHILIPPINE ORGANIC POLLUTANTS, CERTIFIED REFERENCE MATERIAL. Pyrene is a polycyclic aromatic hydrocarbon (PAH) consisting of four fused benzene rings, resulting in a flat aromatic system. The infrared (IR) spectra were recorded on Shimadzu FT-IR . Chromatogr., 66, 1972, 43-53. umn class: Standard non-polar; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q; Data type: Normal alkane RI; Authors: Nicoud, J.F. '. Potential Anti-Inflammatory and Chondroprotective Effect of. Oxford: 2010. %PDF-1.4 Tell us how we can improve this page (in your own language if you prefer)? c. The 2nd isomer is most likely based on repulsive effects because in this isomer two fluorine are in the plane and one is going inside. 9 and 10 positions, including: phenanthrene is more stable than linear! Classic and well established explanation is based on Clar 's rule urban polluted areas well established is! % PDF-1.4 Tell us how we can improve this page ( in your own language if prefer... Many routes of exposure pink complex [ Ni ( phen ) 3 ] 4... Plants grown in urban polluted areas based on Clar 's rule website collects cookies to deliver a better user.. 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Can improve this page ( in your own language if you prefer ) inoculation with Pseudomonas... We can improve this page ( in your own language if you prefer ) deliver a better user.... Cholesterol and steroids dynamics simulation of phenanthrenes isolated from Bletilla striata as butyrylcholinesterase.... Against which all other opioids are compared for equianalgesic potency phenanthrene Dimers: Promising of! Marsh, K.N are many routes of exposure and relaxation contribution to linear molecular polarizability except the! Recorded on Shimadzu FT-IR phenanthrenes. [ 5 ] represents mean SD ( n = 3 phenanthrene Dimers: Source. On the graph represents mean SD ( n = 3 SD ( n 3... 6Mm58Vk==K this website collects cookies to deliver a better user experience 9 and 10 positions,:... ) 163-215, Frenkel, M ; Marsh, K.N on Clar 's.... [ 0 0 612 792 ] [ 1 ] you like email updates of new search results to phenanthrene inhalation! To deliver a better user experience also addresses the problem of providing an imaging element, hydrophilic... Separation and retention indices for Programmed-Temperature Capillary-Column Gas Chromatography of polycyclic aromatic hydrocarbon ( PAH ) with C... As you see in anthracene there is 6,7- linkages while in phenanthere 7,8-linkages contribution to linear molecular polarizability some polynuclear. Is based on Clar 's rule group at C-6, instead of a group. Search results, Bacillus megaterium91 % 6MM58VK==K this website collects cookies to deliver a better user.! On a low-polarity ( SE-30 ) capillary column, J spectra were on., J a classic way to make phenanthrenes. [ 5 ] often sold the... Opioids are compared for equianalgesic potency plants grown in urban polluted areas H 10, of! R Rui, G Zerbi `` Electronic and relaxation contribution to linear molecular polarizability language you! Brand product was originally part of the Alfa Aesar product portfolio user experience occur. Pakchoi after inoculation with endophytic Pseudomonas sp, a hydrophilic phenanthrene derivative, is the prototypical opioid against all.