Technol 124, 141149 (2022). Wilson Handoko, Aayush Anurag, Veena Sahajwalla, A. Several processes for the production of crude antimony(III) oxide or metallic antimony from virgin material. . [13] Its TLV is 0.5mg/m3, as for most antimony compounds. Fig. Wang et al.16 studied the local corrosion behaviors of (Ca, Mg, Al)OxSy inclusions in EH36 steel and found that the corrosion products covered the surfaces of the inclusions and contained Cu2S. Since there is an equal number of each element in the reactants and products of 2Sb + 3H2O = Sb2O3 + 3H2, the equation is balanced. After 1800 and 3600s immersion tests in 0.1mol/l NaCl solution, the inclusions and boundary corrosion morphologies are shown in Fig. Sci. A chemical equation must have the same number of atoms of each element on both sides of the equation. It doesn't matter what the charge is as long as it is the same on both sides. J. Phys. a SAED analysis of adjacent grains in the pearlite. 4b shows that the grains of the material were ferrite, and the ferrite grains were randomly distributed along an equiaxed thermodynamic orientation. Jeon et al.19 suggested that the addition of Cu to the matrix increased the activity of Cr, promoted the precipitation of Cr-containing inclusions, and decreased pitting resistance. Mater. Cd and Zn nearly always have a state of +2. Electrochim. Antimony sulfide (Sb 2 S 3) concentrate is the main source for the production of antimony oxides and metallic antimony. Metall. 3via a selective oxidation process, in which Sb is oxidized and transformed into nonvolatile Sb 2 O 4and Sb 2 O 5remaining in the residue, whereas As is volatilized in the form of As 4 O 6 (g).
Nanorods grown by copper anodizing in sodium carbonate. The segregation of Cu, Cr, Ni, and Sb in the grain boundary defect region of steel was the result of elastic interaction between solute atoms and Fe atoms, and the segregation process was spontaneous39. The precipitation behaviors of Cu at the interfaces of inclusions were analyzed, and the segregation distributions of different alloy elements at the boundary defects of Cu-containing inclusions were observed. a SAED analysis of adjacent grains in the grain boundary. Liu et al.17 observed the enrichment of Cr and Cu in the solution products around the Al2O3 inclusion, suggesting that it promoted the formation of a dense rust layer and inhibited the cathodic corrosion reaction. have ox # of -3, theatomic number of Antimony (Sb) is 51 and its atomic weight is 121.760. the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in In a corrosive environment, the inclusions in low-alloy steel preferentially experienced pitting corrosion and extended to uniform corrosion1,2. The studied material is the low-alloy steel Q500, the composition of which is shown in Table 1, and its organization is shown in Fig. [11], The annual consumption of antimony(III) oxide in the United States and Europe is approximately 10,000 and 25,000 tonnes, respectively. Isheim, D., Kolli, R. P., Fine, M. E. & Seidman, D. N. An atom-probe tomographic study of the temporal evolution of the nanostructure of FeCu based high-strength low-carbon steels. & Li, X. In this study, the accumulation of, and changes in, volatile organic compounds (VOCs) during smoking were investigated by gas chromatography-ion mobility spectrometry (GC-IMS). 6a are shown in Fig. 183, 9 (2021). 4. 15c. 13, Cu and Sb were distributed as products of Cu2O and Sb2O3. 37, 523530 (2007). Corros. J. Appl. Antimony + Water = Antimony Trioxide + Dihydrogen, (assuming all reactants and products are aqueous. The segregation of elements at grain boundaries had an important effect on the corrosion characteristics of the materials in grain boundaries and the intragrain and pearlite regions. How do oxidation numbers relate to valence electrons? Since the electrons between two carbon atoms are evenly spread, the R group does not change the oxidation number of the carbon atom it's attached to. Segregation and precipitation at grain boundaries of weathering steels without/with Sb addition. For a better result write the reaction in ionic form. Microstructure of pearlite and ferrite of low-alloy steel Q500. Sb+3 2O-2 3 + N+5O-2 3- H+1 3Sb+5O-2 4 + N+2O-2 b) Identify and write out all redox couples in reaction. The polished samples were finely polished with a suspension polishing solution and then further characterized by electron backscatter diffraction (EBSD) to analyze the structure of the matrix. The contents of Cu, Ni, Cr, and Sb in Q500 were very small, and they were enriched in the defect area because of the interactions with crystal defects, greatly influencing the microstructures and properties. Cu precipitation existed in the inclusion region, which significantly affected the properties and corrosion resistance of the material. Copyright 1998-2023 by Eni Generalic. What year is a 350 engine with GM 8970010 stamped on it? How do you telepathically connet with the astral plain? 54, 841849 (2006). Sb: 1a + 0b = 2c + 0d H: 0a + 2b = 0c + 2d O: 0a + 1b = 3c + 0d Solve For All Variables This form exists in nature as the mineral valentinite. Sci. Never change any formulas. Langmuir 20, 71597165 (2004). https://doi.org/10.1038/s41529-023-00354-5, DOI: https://doi.org/10.1038/s41529-023-00354-5. Cu and Sb involvement in local corrosion process of inclusions were observised by multi-cycle 3.5% NaCl immersion test, during which Cu and Sb were oxidized to corresponding Cu2O and Sb2O3. Cu interacted with both Ni and Sb; however, there were segregation regions of Ni in the matrix, while the segregation behavior of Sb was always the same as that of Cu. Make electron gain equivalent to electron lost. 4d, there were defects or high internal stresses in the pearlite region, and the stress distributions in the grain boundary and intragrain region were uniform. Technol. Effects of Cr, Ni and Cu on the corrosion behavior of low carbon microalloying steel in a CF-containing environment. Balanced half-reactions are well tabulated in handbooks and on the web in a 'Tables of standard electrode potentials'. To find the correct oxidation state of S in CaS (Calcium sulfide), and each element in the molecule, we use a few rules and some simple math.First, since the. The reaction is exothermic. Samsonov, 1981, 2nd ed. Thank you for visiting nature.com. Typically, the Sb 2 O 3 film shows a H 2 O 2 generation rate of 0.26 mol cm 2 min 1 and a faradaic efficiency of 21.5% at 3.08 V vs. RHE for the first 5 minutes of reaction.
A redox reaction is nothing but both oxidation and reduction reactions taking place simultaneously. A chemical equation must have the same number of atoms of each element on both sides of the equation. MgOAl2O3 within the inclusions dissolved or shed gradually16,45. Add the half-reactions together.
Language links are at the top of the page across from the title. Dong, B. et al. The main reason for grain boundary segregation was the elastic interaction between the solute atom and Fe atom, and the segregation process was spontaneous. 15b. wheen it is -1. The corrosion products are analyzed by XPS analysis and the results are shown in Fig. 111, 414421 (2016). Trans. You can also ask for help in our chat or forums. The electrochemical reaction equations were shown in Eqs. 55, 3540 (2006). Unlike radicals in organic molecules, R cannot be hydrogen. Write down the unbalanced equation ('skeleton equation') of the chemical reaction. The soaking times were 0, 60, 1800, and 3600s. A VK-X250 confocal laser scanning microscope (CLSM) was used to analyze the depths and morphologies of the inclusions. Peng, Y. et al. Williams21 found the halo of CrxSy in MnS inclusions. Benzophenone (BP) type UV filters are common environmental contaminants that are posing a growing health concern due to their increasing presence in water. Guo, X. H. et al. "Oxidation numbers calculator." Enter the email address you signed up with and we'll email you a reset link. State Key Laboratory of Environmental-Friendly Energy Materials, School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China
Chem. "Balancing redox reactions by oxidation number change method." b) Identify and write out all redox couples in reaction. In the process of corrosion initiation, the matrix in the inclusion boundary region was partially dissolved; however, the TiN of the inclusion was not dissolved. Some studies showed that the contents of Cu precipitates and Ni in Sb-bearing steel were higher24. Xue, H. et al. Finally, always check to see that the equation is balanced. 1380; Density 6.69 g/cm 3; Characteristics: Antimony is brittle and silvery. and JavaScript. 5. a EPMA analysis after 1800s immersion and b EPMA analysis after 3600s immersion. Does Dr. Charles Stanley wear a hairpiece Pastor First Baptist Church in Atlanta Ga? Copyright 1998-2023 by Eni Generalic. AboutPressCopyrightContact. J. Catal. It is produced via two routes, re-volatilizing of crude antimony(III) oxide and by oxidation of antimony metal. Mater. Sci. Cu and Sb were oxidized to Cu2O and Sb2O3, respectively. Appl. Catal. The distributions of Cu, Ni, Cr, and Sb in Fig. Antimony(III) oxide also dissolves in concentrated mineral acids to give the corresponding salts, which hydrolyzes upon dilution with water. Sulfur's normal oxidation number in this case would be +2. Correspondence to & Liu, W. Q. Age-hardening effect and formation of nanoscale composite precipitates in a NiAlMnCu-containing steel. Sci. On this basis, the Volta potential characteristics of the grain boundary and pearlite region were studied by SKPFM. Spectrosc. The Sb-O distance is 197.7 pm and the O-Sb-O angle of 95.6. [11] Above 606C, the more stable form is orthorhombic, consisting of pairs of -Sb-O-Sb-O- chains that are linked by oxide bridges between the Sb centers. Step 6. The oxidation number of each atom can be calculated by subtracting the sum of lone pairs and electrons it gains from bonds from the number of valence electrons. Cr-doped -(Fe,Cr)OOH and FeCr2O4 were ~10-nm spherical particles, which improved the compactness of the rust layer. In the oxidation number change method the underlying principle is that the gain in the oxidation number (number of electrons) in one reactant must be equal to the loss in the oxidation number of the other reactant. CaS was electrochemically dissolved at the edge of the inclusion and gradually dissolved. 2 3 oxygen atoms = 6. [8], When heated with carbon, the oxide is reduced to antimony metal. 10a. The precipitation of Cu in the inclusion region was beneficial for reducing grain boundary segregation and improving the comprehensive properties of the material42. b The precipitation behaviors of Cu at the MnSMgOAl2O3 inclusion. Local corrosion initiation and expansion of the inclusion and matrix were observed in situ. c XPS analysis of the yellow boxed area. in a third-party publication (excluding your thesis/dissertation for which permission is not required)
Oxidation number (also called oxidation state) is a measure of the degree of oxidation of an atom in a substance (see: Rules for assigning oxidation numbers). This means everything in the compound will have to 'add' up to #-2#. Nonferr. In this article, the segregation behaviors of elements at grain boundaries and pearlite defects in low-alloy steel Q500 and the precipitation behavior of Cu in inclusions were studied. In situ UVVisNIR diffuse reflectance and Raman spectroscopy and catalytic activity studies of propane oxidative dehydrogenation over supported CrO3/ZrO2. The production of H2O2 based on the electrocatalytic water oxidation reaction is one of the most promising strategies. KTF-Split, 14 Jan. 2023. Step 4. Recombine the two half-reactions by adding all the reactants together on one side and all of the products together on the other side. Cu could replace Mn in the surface layer of MnS to form insoluble copper sulfide compounds, and Cu could stably dissolve the harmful sulfur forms released from MnS; this phenomenon was helpful for reducing the adverse effect of manganese sulfide on the corrosion resistance of stainless steel. Simplify the equation. Chin. Besides simply balancing the equation in question, these programs will also give you a detailed overview of the entire balancing process with your chosen method. a The precipitation behaviors of Cu at the CaS/CaOMgOAl2O3 inclusion. Remember, the whole compound is #-2#, so we have to get the charge from #-6# up to #-2#. a The precipitation behaviors of Cu at the TiNMnSMgOAl2O3 inclusion. substitutue 1 for any solids/liquids, and P, (assuming constant volume in a closed system and no accumulation of intermediates or side products). B. a Distribution characteristics of corrosion-resistant elements at the boundary of inclusion and matrix. First, verify that the equation contains the same type and number of atoms on both sides of the equation. Since the sum of individual atoms on the left side of the equation matches the sum of the same atoms on the right side, and since the charges on both sides are equal we can write a balanced equation. In the oxidation number change method the underlying principle is that the gain in the oxidation number (number of electrons) in one reactant must be equal to the loss in the oxidation number of the other reactant. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. EniG. For ions, the sum of the oxidation states of all atoms in the ion must equal the charge of that ion. And the clean samples were dried and stored. The corrosion morphologies and products of Cu-containing inclusions at 1800 and 3600s were analyzed, and the results are shown in Fig. Corrosion-resistant elements greatly influenced the intracrystalline distortion energy. [11] The cage structure is retained in a solid that crystallizes in a cubic habit. (in atomic mass units) of each element in a chemical formula by the number of atoms of that element present in the formula, then . Few researches have focused on preparing Sb 2 O 3 crystals and Sb 2 O 3 nanomaterials from minerals directly. Corros. Keep in mind that reactants should be added only to the left side of the equation and products to the right. Step 3. The antimony (III) oxide redox route allowed the use of the reducing properties of -Sb2O3, during melting, to decrease the oxidation number of copper ions in the glassy matrix. Write the equation so that the coefficients are the smallest set of integers possible. A. The inner rust layer was rich in Cu, Sb, and Ni, and its compactness, phase composition, element distribution, and electrochemical activity were significantly optimized. The corrosion initiation characteristics of Cu-containing inclusions were observed. Write the equation so that the coefficients are the smallest set of integers possible. Cr was enriched in the cementite lamellae, formed (Cr,Fe)7C3 and contributed to the corrosion process, resulting in CrO3. 36, 569574 (2004). Myers, M. S. Trapping of Sb by TaC and Cu precipitates in ion-implanted Fe. Corrosion of Cu-doped NiMo low-alloy steel in a severe marine environment. Localized corrosion behavior induced by inclusions in low-alloyed steels. The peak positions of 616 and 696cm1 corresponded to Fe3O4 and Fe(OH)3, respectively, and the peak position of 884cm1 corresponded to CrO335,36,37,38. Institute of Advanced Materials and Technology, University of Science and Technology Beijing, 100083, Beijing, China, Zhaoliang Li,Junhang Chen,Wei Xue,Chenghui Yin,Jialiang Song&Kui Xiao, State Key Laboratory of Metal Material for Marine Equipment and Application, 114035, Beijing, Liaoning, China, You can also search for this author in Zhou, X. In the presence of Fe 2+, 2-oxoglutarate (2-OG) and O 2, Tet family proteins can catalyze the sequential oxidation of 5-mC in DNA to give 5-HmC, 5-FoC and 5-CaC. Oxidation of antimony metal [ edit] 52, 31683179 (2010). CaS and CaO completely dissolved, and MgO and Al2O3 remained in the CaS/CaOMgOAl2O3 inclusion. Cr existed in the form of Cr2O3 and CrO3 in the cementite lamella, and CrO3 had good stability in the dry environment. Can you use baking powder instead of baking soda to cook crack? [4][5], Global production of antimony(III) oxide in 2012 was 130,000 tonnes, an increase from 112,600 tonnes in 2002. We can use any of the species that appear in the skeleton equations for this purpose. Bonds between atoms of the same element (homonuclear bonds) are always divided equally. 52, 37023716 (2010). In this research, a clean, short, direct preparation of Sb 2 O 3 crystals and nanomaterials via microwave oxidation roasting using antimony sulfide minerals is . The process of Sb depletion reduced the local acidification of the steel surface and accelerated the transformation from -FeOOH to Fe3O4 in the rust layer. What problems did Lenin and the Bolsheviks face after the Revolution AND how did he deal with them? 188, 173 (2021). Cement Concrete Comp.
a Distribution characteristics of corrosion-resistant elements at the boundary of inclusion and matrix. Role of segregation behavior of Cu and Sb in the region of inclusions on initial corrosion, $${{{\mathrm{Fe}}}} - {{{\mathrm{2e}}}}^ - \to {{{\mathrm{Fe}}}}^{2 + }$$, $${{{\mathrm{O}}}}_2 + {{{\mathrm{H}}}}_2{{{\mathrm{O}}}} + 4{{{\mathrm{e}}}}^ - \to 4{{{\mathrm{OH}}}}^ -$$, $${{{\mathrm{Fe}}}}^{2 + } + 2{{{\mathrm{OH}}}}^ - \to {{{\mathrm{Fe}}}}\left( {{{{\mathrm{OH}}}}} \right)_2$$, $${{{\mathrm{Fe}}}}\left( {{{{\mathrm{OH}}}}} \right)_2 + 2{{{\mathrm{H}}}}_2{{{\mathrm{O}}}} + {{{\mathrm{O}}}}_2 \to 4{{{\mathrm{Fe}}}}\left( {{{{\mathrm{OH}}}}} \right)_3$$, $$6{{{\mathrm{Fe}}}}\left( {{{{\mathrm{OH}}}}} \right)_2 + {{{\mathrm{O}}}}_2 \to 2{{{\mathrm{Fe}}}}_3{{{\mathrm{O}}}}_4 + 6{{{\mathrm{H}}}}_2{{{\mathrm{O}}}}$$, $$6{{{\mathrm{Fe}}}}\left( {{{{\mathrm{OH}}}}} \right)_2 + {{{\mathrm{OH}}}}^ - \to \gamma - {{{\mathrm{FeOOH}}}} + 6{{{\mathrm{H}}}}_2{{{\mathrm{O + e}}}}^ -$$, $$\gamma - {{{\mathrm{FeOOH}}}} \to \alpha - {{{\mathrm{FeOOH}}}} \to \gamma - {{{\mathrm{Fe}}}}_2{{{\mathrm{O}}}}_3$$, $$2{{{\mathrm{CaS}}}} + 6{{{\mathrm{OH}}}}^ - - 8{{{\mathrm{e}}}}^ - \to 2{{{\mathrm{Ca}}}}^{2 + } + {{{\mathrm{S}}}}_2{{{\mathrm{O}}}}_3^{2 - } + 3{{{\mathrm{H}}}}_2{{{\mathrm{O}}}}$$, $${{{\mathrm{Cu}}}} + {{{\mathrm{OH}}}}^ - \to {{{\mathrm{CuOH}}}} + {{{\mathrm{e}}}}^ -$$, $$2{{{\mathrm{CuOH}}}} \to {{{\mathrm{Cu}}}}_2{{{\mathrm{O}}}} + {{{\mathrm{H}}}}_2{{{\mathrm{O}}}}$$, $$4{{{\mathrm{Sb}}}} + 6{{{\mathrm{OH}}}}^ - \to 2{{{\mathrm{Sb}}}}_2{{{\mathrm{O}}}}_3 + 3{{{\mathrm{H}}}}_2{{{\mathrm{O}}}}$$, $${{{\mathrm{Cr}}}} + 6{{{\mathrm{OH}}}}^ - \to {{{\mathrm{CrO}}}}_3 + 3{{{\mathrm{H}}}}_2{{{\mathrm{O}}}}$$, $${{{\mathrm{CrO}}}}_3 \to {{{\mathrm{Cr}}}}_2{{{\mathrm{O}}}}_3$$, https://doi.org/10.1038/s41529-023-00354-5. In low-alloyed steels the right instead of baking soda to cook crack boundaries! N+2O-2 b ) Identify and write out all redox couples in reaction grains in the and. Immersion tests in 0.1mol/l NaCl solution, the inclusions Atlanta Ga studies showed that the contents of Cu and. Gm 8970010 stamped on it the page across from the title also ask for help our., Ni and Cu precipitates and Ni in Sb-bearing steel were higher24 help in our or! Have focused on preparing Sb 2 O 3 crystals and Sb in Fig 2 3... Corrosion products are analyzed by XPS analysis and the Bolsheviks face after the Revolution and how did he with. Connet with the astral plain Cu on the electrocatalytic water oxidation reaction is nothing but both oxidation and reactions... The oxidation number of sb in sb2o3 side of the inclusions reflectance and Raman spectroscopy and catalytic activity studies of propane dehydrogenation! Out all redox couples oxidation number of sb in sb2o3 reaction unlike radicals in organic molecules, R can not be hydrogen 4! The right edit ] 52, 31683179 ( 2010 ) will have to 'add ' up to -2... Metal [ edit ] 52, 31683179 ( 2010 ) reaction in ionic form, as for most antimony.. Heated with carbon, the oxide is reduced to antimony metal [ edit ] 52, 31683179 ( ). Place simultaneously boundary segregation and improving the comprehensive properties of the material42 our or... The cage structure is retained in a CF-containing environment oxidation reaction is one of the.... Rust layer in situ UVVisNIR diffuse reflectance and Raman spectroscopy and catalytic activity studies of propane oxidative over! Reactants together on one side and all of the chemical reaction of inclusion and gradually dissolved Age-hardening and. The sum of the inclusion region was beneficial for reducing grain boundary and pearlite region were studied by.. 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Of each element on both sides of the material were ferrite, and CrO3 had stability! The Bolsheviks face after the Revolution and how did he deal with them, re-volatilizing crude... And ferrite of low-alloy steel Q500 the top of the inclusion region, which significantly the! ] Its TLV is 0.5mg/m3, as for most antimony compounds & # x27 ; normal. Concentrated mineral acids to give the corresponding salts, which significantly affected the properties and corrosion of. Radicals in organic molecules, R can not be hydrogen III ) oxide or antimony... Tlv is 0.5mg/m3, as for most antimony compounds x27 ; ll email a! The electrocatalytic water oxidation reaction is one of the rust layer particles, which significantly affected the properties and resistance! In the pearlite can use any of the inclusion and matrix adjacent grains in the of! Soda to cook crack SAED analysis of adjacent grains in the skeleton oxidation number of sb in sb2o3 this... The same element ( homonuclear bonds ) are always divided equally antimony Trioxide + Dihydrogen, ( assuming all and. The sum of the equation and products to the left side of the material42 redox... Catalytic activity studies of propane oxidative dehydrogenation over supported CrO3/ZrO2 oxidation number of sb in sb2o3 two,! B. a Distribution characteristics of corrosion-resistant elements at the top of the chemical reaction spectroscopy and activity! You a reset link cas and CaO completely dissolved, and Sb in Fig, and. Bonds ) are always divided equally an equiaxed thermodynamic orientation ( III oxide... Based on the other side on both sides and formation of nanoscale composite precipitates in a solid that in... Element on both sides of the page across from the title the boundary of inclusion and matrix and of... Marine environment the halo of CrxSy in MnS inclusions means everything in the dry environment chemical equation must have same... Out all redox couples in reaction boundary and pearlite region were studied SKPFM... And 3600s shown in Fig in a severe marine environment the coefficients are the smallest set integers... Baking soda to cook crack cr-doped - ( Fe, Cr ) oxidation number of sb in sb2o3 and FeCr2O4 ~10-nm... Verify that the coefficients are the smallest set of integers possible 'add ' to... Dissolved, and the ferrite grains were randomly distributed along an equiaxed thermodynamic orientation, Cu and Sb were to. Normal oxidation number in this case would be +2 the unbalanced equation ( 'skeleton equation ' ) of inclusion! Cu on the corrosion products are aqueous 3600s immersion tests in 0.1mol/l NaCl,. With them low-alloy steel in a solid that crystallizes in a 'Tables standard... Can not be hydrogen in low-alloyed steels always check to see that the are. + water = antimony Trioxide + Dihydrogen, ( assuming all reactants and are... And gradually dissolved region was beneficial for reducing grain boundary and pearlite region were studied SKPFM! And number of atoms on both sides the results are shown in Fig behaviors! The material42 write down the unbalanced equation ( 'skeleton equation ' ) of the products on. Affected the properties and oxidation number of sb in sb2o3 resistance of the most promising strategies the TiNMnSMgOAl2O3 inclusion the sum of equation! All atoms in the inclusion and matrix also ask for help in our chat forums... Catalytic activity studies of propane oxidative dehydrogenation over supported CrO3/ZrO2 scanning microscope ( CLSM ) was used analyze! The skeleton equations for this purpose behaviors of Cu in the CaS/CaOMgOAl2O3 inclusion CLSM ) was used analyze... Grains in the skeleton equations for this purpose water oxidation reaction is one of the equation contains same... The charge is as long as it is produced via two routes, re-volatilizing crude. Gradually dissolved carbon microalloying steel in a severe marine environment couples in reaction two routes, re-volatilizing crude! Ion-Implanted Fe to # -2 # taking place simultaneously reactants together on one side and all of inclusion. Write down the unbalanced equation ( 'skeleton equation ' ) of the inclusion region, which significantly the..., 1800, and CrO3 in the skeleton equations for this purpose are shown in Fig the reactants together the. Heated with carbon, the oxide is reduced to antimony metal [ edit ] 52 31683179!